The answer is C. The program prints:
3 9

Why?
Python works out everything on the right first, using the old values: b is 3 and a + b is 9. Then it puts them into a and b at the same time.
Trace table
A trace table follows the program step by step. Here’s this one:
| a | b | |
|---|---|---|
| before | 6 | 3 |
| after | 3 | 9 |
The code again
a = 6
b = 3
a, b = b, a + b
print(a, b)
Try it: change one number in the program and predict the new output before you run it.